Everything about Tetrazine totally explained
Tetrazine is an unstable
compound that consists of a six-membered
aromatic ring containing four nitrogen atoms with the molecular formula
C2H2N4. The name
tetrazine is used in the
nomenclature of derivatives of this compound. Three core-ring
isomers exist: 1,2,3,4-tetrazines, 1,2,3,5-tetrazines and 1,2,4,5-tetrazines
1,2,3,4-tetrazines
1,2,3,4-Tetrazines are often isolated fused to an aromatic ring system and are stablized as the dioxide derivatives.
1,2,4,5-tetrazine
1,2,4,5-Tetrazines are very well known and myriad 3,6-disubstituted 1,2,4,5-tetrazines are known . These materials are of use in the area of energetic chemistry.
The compound
3,6-di-2-pyridyl-1,2,4,5-tetrazine has two
pyridine substituents and is of importance as a reagent in
Diels-Alder reactions. It reacts with
norbornadiene in a sequence of one DA reactions and two retro-DA reactions to
cyclopentadiene and a
pyridazine with exchange of an
acetylene unit:
»
With norbornadiene fused to an arene the reaction stops at an intermediary stage
Further Information
Get more info on 'Tetrazine'.
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